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Circulation Classification and Source Analysis of Summer Ozone Pollution in Chengdu
SHI Wenbin, QU Kun, YAN Yu, QIU Peipei, WANG Xuesong, DONG Huabin
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (3): 565-574.   DOI: 10.13209/j.0479-8023.2022.016
Abstract537)   HTML    PDF(pc) (2726KB)(224)       Save
In order to explore the impact of large-scale circulations on O3 pollution in Chengdu, based on the 700 hPa geopotential height field in the Sichuan Basin (SCB) and using the T-PCA method, the atmospheric circulations in the summer of 2015–2019 (June–August) were classified into five circulation patterns, and the characteristics of O3 pollution and O3 sources in Chengdu under different circulation patterns were identified. Among the five types of circulation patterns, the northeast-high pressure (NEH) pattern and the under-high pressure field (UNF) pattern generally led to higher air temperature, and lower humidity and cloud cover in the SCB. Air temperature change compared to the previous days showed an obvious increasing trend in the SCB under the UNF pattern, kept stable under the NEH pattern, and indicated cooling effects with varying intensities under the other three circulation patterns (the southeast-high pressure pattern, the northwest-low pressure pattern and the northwest-high pressure pattern). The meteorological conditions under NEH and UNF were more conducive to the photochemical production of O3 in the SCB. During the study period, O3 concentrations and the percentages of over-standard days of O3 in Chengdu under NEH and UNF were significantly higher than those under the other three circulation patterns, and thus NEH and UNF were the main circulation patterns that were related to O3 pollution in summer. Months with more severe O3 pollution in Chengdu tended to have higher proportion of days under the NEH and UNF patterns. The simulation studies of O3 sources in Chengdu in summer suggested that O3 was mainly derived from the SCB (55.0%), with local contribution of Chengdu (31.6%), and other important contributing cities including Deyang (5.4%), Chongqing (4.0%), Ziyang (3.9%) and Meishan (2.2%). However, O3 sources in Chengdu under different circulation patterns showed different characteristics. Under the NEH pattern, O3 transport within the Chengdu Plain had notable impact on O3 pollution in Chengdu, with a significant increasing contribution from Deyang (14.9%). By contrast, under the UNF pattern, O3 pollution in Chengdu became more localized, with nearly half (46.8%) of O3 contributed by local emissions. 
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Meteorological and Pollution Characteristics of PM2.5 under Atmosphric Circulation Types in Autumn and Winter in Shijiazhuang
XIAO Teng, LIN Tingkun, YAN Yu, WANG Xuesong
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (3): 414-424.   DOI: 10.13209/j.0479-8023.2021.021
Abstract1038)   HTML    PDF(pc) (12978KB)(177)       Save
According to the ground and vertical meteorological characteristics of atmospheric circulation types during the autumns and winters (Nov.?Feb.) of 2013?2018 in Shijiazhuang, 11 types of atmospheric circulation were classified into five categories. The correlation between each category and PM2.5 pollution was discussed by combining the transport trajectories and the air quality data. Among those categories, Category I (type NW and type N, accounting for 16% of days) was the best condition for air pollution diffusion, characterized by the dominant west or northwest winds near surface with steady direction and high speed, as well as high planetary boundary layer (PBL) height. Category II (type NE, accounting for 9%) and Category III (type E and type SE, accounting for 12%) were the second-best conditions, characterized by high wind speed. Category II was dominated by north wind and medium PBL height, while Category III was dominated by northeast wind and low PBL height. Category IV (type A, 37%) was unfavorable for air pollution diffusion, which was characterized by low-speed, near-surface winds and low PBL height. Category V (type UM, type C, type S, type SW, type W, 26%) was the worst condition, characterized by near-surface winds with low speed and variable directions, as well as low PBL height and intensive temperature inversion in lower atmosphere. The potential areas of sources contributing to PM2.5 pollution in Shijiazhuang under different circulation types varied with different transport trajectories. Concerning the correlation between the PM2.5 pollution in Shijiazhuang during the autumns and winters and the diffusive conditions of different circulative types, the PM2.5 pollution tended to occur (the frequency of pollution was from 78% to 96%, and the frequency of heavy pollution and above was more than 55%) when the region was controlled by Category V; the condition of the PM2.5 pollution tended to change slowly under Category IV, but the PM2.5 concentration was more likely to increase under the continuous Category IV days; the frequency of PM2.5 pollution was lowest under Category I.
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Source Apportionment and Transport Characteristics of Ozone in Baoding during Summer Time
HUANG Zhengchao, HONG Linan, YIN Peiling, WANG Xuesong, ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (3): 665-672.   DOI: 10.13209/j.0479-8023.2017.189
Abstract812)   HTML11)    PDF(pc) (6181KB)(246)       Save

Models-3/CMAQ and Brute Force method were applied to simulate the ozone pollution and to analyze how meteorological condition influenced the pollution characteristic and the source apportionment of ozone during July 2014 in Baoding. The distribution of ozone concentration in Baoding gradually increased from west to east. In July, the high ozone episode mainly occurred when southern air mass, southeastern air mass and eastern air mass arrived, and the percentages of polluted days were about 28%, 39% and 17%, respectively. During the maximum eight hours of ozone, background and cross regional transmission contributed about half of concentration of surface ozone. As for the regional contribution, Hebei contributed about 2/5 of the surface ozone. Henan contributed about 1/10 as well as Shandong and Jiangsu. The rapid increasing contribution from central Hebei and influences of vertical transportation from Henan and Shandong province leaded to rapid increasing of surface ozone concentration during the daytime in Baoding; most regional contribution changed gently except for central Hebei area, which resulted in high ozone concentration and long duration in the afternoon as well as the single peak diurnal variation.

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Ozone Source Apportionment of Typical Photochemical Pollution Episodes in the Pearl River Delta in Autumn
CHEN Hao;WANG Xuesong;SHEN Jin;LU Keding;ZHANG Yuanhang
   2015, 51 (4): 620-630.   DOI: 10.13209/j.0479-8023.2015.089
Abstract1295)      PDF(pc) (4166KB)(747)       Save
The Comprehensive Air Quality Model with extensions (CAMx), a 3-D regional chemical transport model, was used to simulate ozone concentrations in the Pearl River Delta (PRD) in November, 2009. Ozone Source Apportionment Technology (OSAT) was applied to investigate sources of two typical ozone episodes and a clean day as comparison. The results showed that emissions from urban Guangzhou and Dongguan mainly contributed to local areas and the southwestern part of PRD (15–30 μL/m3), while emissions from Shenzhen Baoan district (15–25 μL/m3) mainly affected the Pearl River Estuary. Mobile sources and solvent usage sources were two major contributors to ozone formation and had an influence in most areas of the central and western PRD. Mobile sources could contribute as much as 50 μL/m3 hourly ozone concentration to the boarding area of Foshan and Guangzhou. Trans-boundary import of ozone made episodes more likely to occur in PRD under unfavorable weather conditions, however, the ozone precursors emitted within the PRD region were the main cause of high ozone concentrations during ozone episodes. As a result, the strategies on controlling emissions within the PRD region are the key to the reduction of ozone pollutions in PRD.
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Impact of Typical Meteorological Conditions on the O3 and PM10 Pollution Episodes in the Pearl River Delta in Autumn
ZHANG Haoyue,WANG Xuesong,LU Keding,ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract754)      PDF(pc) (5988KB)(1545)       Save
The Community Multi-Scale Air Quality (CMAQ) modeling system was applied to simulate the meteorology field, O3 and PM10 in the Pearl River Delta (PRD) region in the autumn of 2008, in order to elucidate the impact of the typical meteorological conditions on the O3 and PM10 pollution episodes. It was found that PRD pollution characteristics presents periodic variation affected by cold air processes in the autumn of 2008. In general, good air quality was presented when cold air passing through while serious pollution was took place before and after the cold air invasion. 1) Before the cold air invasion, when the weather system “cold front front part” was presented, the height of the mixing layer was often low due to a presence of temperature inversion. Therefore, the PM10 emitted or formed at night was continuously accumulated in the morning hours causing the air pollution in northern and central PRD; the afterwards transport of the O3 during daytime and PM10 during nighttime with northern wind would cause the air pollution in southern PRD. 2) Before the cold air invasion, when the weather system “high-pressured base” was presented, an inversion layer was built up to prevent vertical mixing; both O3 and PM10 was then mainly horizontally transported with northeasterly wind; consequently forming air pollution in southwestern PRD. 3) After the cold air invasion, under the control of a ridge high pressure type of weather condition, temperature inversion was built up near the surface and a stagnant condition was presented; thus, O3 and PM10 was trapped in the source regions such as western, northwestern and central PRD, resulted in serious local pollutions.
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Characteristics of the Spatial Distributions of Ozone-Precursor Sensitivity Regimes in Summer over Beijing
NIE Teng,LI Xuan,WANG Xuesong,SHAO Min,ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract878)      PDF(pc) (610KB)(839)       Save
Models-3/CMAQ was applied to simulate the ozone-precursor sensitivity during June, July, and August, 2010 in Beijing. Frequencies of ozone-precursor sensitivity regimes were used to represent the characteristics of the spatial distributions of the regimes. Results showed that ozone formation was VOCs-sensitive in urban Beijing, and turned to be mixed sensitive and NOx-sensitive in suburban areas and more remote areas of Beijing. In urban Beijing, the number of days that a reduction of anthropogenic VOCs could reduce ozone efficiently accounted for about 50% of the whole summer; while in Changping, Yanqing and Huairou, the number of days that a reduction of anthropogenic NOx could reduce ozone efficiently accounted for 40%~50%. The situation that ozone gave little response to the reduction of both two precursors occurred in every district/county. The number of days in this situation accounted for more than 70% in eastern and southern districts/counties. The distributions of the sensitivity regimes of maximum 8-hour ozone concentration were similar to that of 1-hour ozone concentration.
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Interaction of Ambient PM10 among the Cities over the Pearl River Delta
HU Xiaoyu,LI Yunpeng,LI Jinfeng,WANG Xuesong,ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract505)            Save
The Models-3/CMAQ modeling system was applied to investigate PM10 pollution over the Pearl River Delta (PRD) region during October 2006. Sensitivity analysis was conducted to examine the relationship between the reduction of different source emissions and the consequent change of PM10 concentrations, and to quantify the interaction of air pollution among adjacent cities. The results show that PM10 pollution is a regional-scale issue in PRD. Guangzhou, Foshan, Jiangmen, and Dongguan contribute to the PM10 in PRD remarkably. The relative sensitivity coefficient was proposed to determine the impact of regional pollution sources. The PM10 concentrations in Zhuhai, Jiangmen, Zhongshan, and Foshan cities are significantly influenced by regional source emissions. The intercity transport has been the important factor of PM10 pollution in PRD. To improve the air quality in PRD area, effective control of emission sources should be highly reinforced, together with consentaneous programming, intensive collaboration, joint prevention and control.
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A Novel Method for Characterizing Acid-Base Properties of Atmospheric Particulate Matter
SUN Qian,HUO Mingqun,XIE Peng,LI Jinlong,BAI Yuhua,LIU Zhaorong,WANG Xuesong
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract711)            Save
Six representative acid-base components are proposed to quantitatively characterize acid-base properties of particulate matter. Micro-titration and determination of water-soluble ion concentrations are applied to water-soluble particulate matter extract, then the acid-base balance principle and the principle of charge conservation are adopted to calculate the concentrations of representative components. Polynomial regression is conducted to analyze the relationship between the amounts of hydrogen ions neutralized by particulate matter of unit mass and the initial pH values of absorption solutions, and a series of empirical equations are obtained, which are applicable to estimate the change in pH derived by the particles absorbed by the precipitation with lower ion concentrations.
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Construction Fugitive PM10Emission and Its Influences on Air Quality in Guiyang
ZHANG Wenting,WANG Xuesong,LIU Zhaorong,ZHANG Yuanhan,SHAO Min,CHENG Qun,WU Degang,IAN Wei
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract684)            Save
To study influences of construction fugitive in Guiyang, construction fugitive PM10emission in 2002 was estimated based on an extensive survey of construction activities in Guiyang. The contribution of construction fugitive dust to ambient PM10was simulated using the CALPUFF model, and the seasonal variation as well as influencing factors were addressed. The results show that fugitive PM10emission from construction activities was up to 416 tons, accounting for 4% of all PM10 source emissions in the urban area of Guiyang. Construction fugitive dust showed great impact on the ambient PM10level in Guiyang, and contributed 12% to the annual mean concentration of PM10over the urban area. Significant seasonal variation of the contribution of construction fugitive dust was found due to the change of construction activities and meteorological conditions ( wind and precipitation).
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Chemical Characters and Sources Identification of PM_10 in Guangzhou Area
CUI Mingming,WANG Xuesong,SU Hang,ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract608)            Save
PM10 samples were collected from seven sites in Gua ngzhou area and associated chemical species including seventeen elements(Na, Mg,Al, K, Ca, Ti, V, Mn, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, and Pb), five water solub le ions(SO2-, NO-, F-,Cl- and NH4+) ,and organic an d elemental carbons were a nalyzed. This paper discusses chemical characters, the changes of PM10 and maincomponents under different meteorological conditions, and also sources identification of PM10 by principal factor analysis. The results indicated that the averagePM10 concentration was 125.8μg/m3 and organic matter, sulfate and crustal dustwere maj or components with proportions of 24%-32% ,17%-21% and 10%-12%, respective ly in the seven sites. Principal factor analysis indicated that soil dust, oil burning, industry source(including metallurgy, chemistry and electric industry), coalburning, secondary source (by photochemical reaction) and biomass burning were t he main sources of PM10, accounting for 20.7%, 17.8%, 16.3%, 14.3%, 10.4%, and 6.3%, respectively of the total variance in the data set.
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Current Status of Nitrogen Oxides Related Pollution in China and Integrated Control Strategy
ZHOU Wei,WANG Xuesong ,ZHANG Yuanhang,SU Hang,LU Keding
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract535)            Save
Current status of nitrogen oxides-related pollution in China was analyzed, including NOx pollution and the related pollution of ozone, acid rain,particulate matter. Then the NOx and related air quality standards were reviewed. Finally, strategy for integrated and multi-target control of NOx pollution were put forward: executing ozone air quality standard, establishing the regional photochemical smog monitoring network; pursuing air quality modeling and control for Beijing, Pearl River Delta etc megacities; strengthening the control of NOx emission from power station and vehicles and setting NOx-related scientific research program.
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The Issues of Application for the Fission Track Dating and Its Geological Significance
ZHANG Zhicheng,WANG Xuesong
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract883)            Save
Unlike most methods of radiometric dating, fission track dating measures the effect, rather than the products, of radioactive decay events. External detector dating method can calculate individual grain ages. There are three assembled ages for single sample, which are pooled age, mean age and central age. It is very important that the fission track ages have no unambiguous geological significance. Tracks are randomly oriented in three dimensional space. However, the measurements of track density used in age eterminations are based on a two dimensional sample of tracks intersecting an internal surface. With the increasing of the temperature, the fission tracks are progressively shortened from their ends, resulting in a reduction in the observed area density of the tracks and therefore a reduction in the measured fission track age. Because the fission track age is associated with the length of tracks, the length and distribution of tracks are the most important parameters in the fission track analysis. By modelling of thermal histories from apatite fission track data, the thermal histories of samples can be reconstructed.
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Investigation of the Mechanisms of Isoprene and Monoterpene Emissions from Hevea brasiliensis in Xishuangbanna
WANG Zhihui,BAI Yuhua,WANG Xuesong,LIU Zhaorong
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract820)            Save
Based on the authors investigation of the isoprene and monoterpene emissions from Hevea brasiliensis (H.B.K) Muell.-Arg in Xishuangbanna, it was found that the isoprene emission was low (emission factor varies between 0 and 1μgC·g-1h-1) and the monoterpene emissions were high (emission factor varies between 10 and 100μgC·g-1h-1). It was presumed that the scarcity of the isoprene synthase in the chloroplast of hevea brasiliensis leaves dominated the special emission character.
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A Numerical Simulation Study of PM10 Pollution in Beijing during Summer Time
WANG Xuesong,LI Jinlong
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract612)            Save
A 3-D Eulerian regional air quality model, CAMx, is used to simulate the temporal variation and spatial distribution of PM10 in Beijing during summertime. The results show the prominent temporal and spatial variation characters of PM10. PM10 diurnal variation shows peaks around midnight and in the morning, an increasing trend around noon in urban areas because of the secondary aerosol production from photochemical reactions, a lowest concentration in early evening. The spatial distribution of PM10 has close relation to the source emission and is affected by the secondary aerosol production from photochemical reactions around noon. The secondary aerosol is an important portion of PM10. The secondary aerosol plays a main role on the concentration variation of sulfate and nitrate, while the concentration level and variation of organic carbon aerosol and PM10 is determined mainly by the primary aerosol.
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A Case Study of Ozone Source Apportionment in Beijing
WANG Xuesong,LI Jinlong
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract641)            Save
The Comprehensive Air Quality Model with extensions (CAMx), a 3-D Eulerian regional air quality model, was used to simulate the tropospheric photochemical pollution in Beijing and Tianjin areas. Ozone Source Apportionment Technology (OSAT) was applied to track the contributions of multiple source areas and source categories to ozone formation in Beijing. The results showed that the source emissions in the urban and suburban areas of Beijing contributed much to ozone formation in local and downwind areas; among all the source categories, mobile source contributed most to ozone formation, followed by the pollutants from oil products and organic solvents and those emitted by industrial source, while biogenic source and other anthropogenic area source contributed less in Beijing. The results also showed that the ozone episode in Beijing area was regional in extent, meteorological fields and pollutant emissions were important impact factors to ozone formation and distribution.
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